【1】国家自然科学基金面上项目，21772071，负责人；
【2】国家自然科学基金面上项目，21472077，负责人；
【3】国家自然科学基金青年77779193永利基金项目，21202073，负责人；
【4】甘肃省自然科学基金项目，20JR10RA608，负责人；
【5】国家“重大新药创制”科技重大专项子课题，2012ZX09201-101 -003，参与。

      1.Hou, S.-H.; Tu, Y.-Q.*; Liu, L.; Zhang, F.-M.; Wang, S.-H.*; Zhang, X.-M., Divergent and Efficient Syntheses of the Lycopodium Alkaloids (−)-Lycojaponicumin C, (−)-8-Deoxyserratinine, (+)-Fawcettimine, and (+)-Fawcettidine. Angewandte Chemie International Edition 2013, 52 (43), 11373-11376.

　　2.Chen, Z.-M.; Zhang, Z.; Tu, Y.-Q.*; Xu, M.-H.; Zhang, F.-M.; Li, C.-C.; Wang, S.-H.*, A Mn(iii)/TEMPO-co-mediated tandem azidation-1,2-carbon migration reaction of allylic silyl ethers. Chemical Communications 2014, 50 (74), 10805-10808.

　　3.Peng Rui, Y. B., Chen Zhimin, Xu Li, Wang Shaohua*, Copper-Catalyzed Trifluoromethylation of Enol Ether. Chinese Journal of Organic Chemistry 2014, 34 (5), 980-984.

　　4.Tian, J.-M.; Zhao, X.; Tu, Y.-Q.*; Gong, W.; Zhang, F.-M.; Zhang, S.-Y.; Wang, S.-H.*, A Synthetic Approach for Constructing the 3/6/6/5-Fused Tetracyclic Skeleton of Tenuipesine A. Chemistry – An Asian Journal 2014, 9 (3), 724-727.

　　5.Wang, S. H.; Tu, Y. Q.; Tang, M., 3.16 The Semipinacol Rearrangements. In Comprehensive Organic Synthesis II (Second Edition), Knochel, P., Ed. Elsevier: Amsterdam, 2014; pp 795-852.

　　6.Wang, S.-H.; Li, B.-S.; Tu, Y.-Q.*, Catalytic asymmetric semipinacol rearrangements. Chemical Communications 2014, 50 (19), 2393-2408.

　　7.Xu, L.; Mou, X.-Q.; Chen, Z.-M.; Wang, S.-H.*, Copper-catalyzed intermolecular azidocyanation of aryl alkenes. Chemical Communications 2014, 50 (73), 10676-10679.

　　8.Mou, X.-Q.; Xu, L.; Wang, S.-H.*; Yang, C., Copper-catalyzed dicyanation of N,N-disubstituted formamide. Tetrahedron Letters 2015, 56 (21), 2820-2822.

　　9.Mou, X.-Q.; Xu, Z.-L.; Wang, S.-H.*; Zhu, D.-Y.; Wang, J.; Bao, W.; Zhou, S.-J.; Yang, C.; Zhang, D., An Au(i)-catalyzed rearrangement/cyclization cascade toward the synthesis of 2-substituted-1,4,5,6-tetrahydrocyclopenta[b]pyrrole. Chemical Communications 2015, 51 (60), 12064-12067.

　　10.Yang, C.; Xu, Z.-L.; Shao, H.; Mou, X.-Q.; Wang, J.; Wang, S.-H.*, A Tin(IV) Chloride Promoted Tandem C?O Bond Cleavage/Nazarov Cyclization/Nucleophilic Addition Reaction of 1,1-Disubstituted Allylic Ethers toward the Synthesis of Multisubstituted Indenes. Organic Letters 2015, 17 (21), 5288-5291.

　　11.Zhu, D.-Y.; Xu, M.-H.; Tu, Y.-Q.*; Zhang, F.-M.; Wang, S.-H.*, Catalytic Asymmetric Construction of α-Quaternary Cyclopentanones and Its Application to the Syntheses of (−)-1,14-Herbertenediol and (−)-Aphanorphine. Chemistry – A European Journal 2015, 21 (44), 15502-15505.

　　12.Zhu, D.-Y.; Zhang, Z.; Mou, X.-Q.; Tu, Y.-Q.*; Zhang, F.-M.; Peng, J.-B.; Wang, S.-H.*; Zhang, S.-Y., Gold(I)/Copper(II)-Cocatalyzed Tandem Cyclization/Semipinacol Reaction: Construction of 6-Aza/Oxa-Spiro[4.5]decane Skeletons and Formal Synthesis of (±)-Halichlorine. Advanced Synthesis & Catalysis 2015, 357 (4), 747-752.

　　13.徐力, 王., 李辉, 阿托伐他汀的合成. 有机化学 2015, 35 (7), 1559-1564.

　　14.Dou, Q.-Y.; Tu, Y.-Q.*; Zhang, Y.; Tian, J.-M.; Zhang, F.-M.; Wang, S.-H.*, Spiro-Pyrrolidine-Catalyzed Asymmetric Conjugate Addition of Hydroxylamine to Enals and 2,4-Dienals. Advanced Synthesis & Catalysis 2016, 358, 874.

　　15.Mou, X.-Q.; Xu, Z.-L.; Xu, L.; Wang, S.-H.*; Zhang, B.-H.; Zhang, D.; Wang, J.; Liu, W.-T.; Bao, W., The Synthesis of Multisubstituted Pyrroles via a Copper-Catalyzed Tandem Three-Component Reaction. Organic Letters 2016, 18 (16), 4032-4035.

　　16.Wang, J.; Mou, X.-Q.; Zhang, B.-H.; Liu, W.-T.; Yang, C.; Xu, L.; Xu, Z.-L.; Wang, S.-H.*, A metal-free addition/dearomatizationΓÇôcyclization/decarboxylation cascade of aryl 3-arylpropiolate toward the synthesis of 1,1-diaryl-2-alkyl-substituted ethylenes. Tetrahedron Letters 2016, 57 (11), 1239-1242.

　　17.Xu, X.-T.*; Mou, X.-Q.; Xi, Q.-M.; Liu, W.-T.; Liu, W.-F.; Sheng, Z.-J.; Zheng, X.; Zhang, K.; Du, Z.-Y.; Zhao, S.-Q.; Wang, S.-H.*, Anti-inflammatory activity effect of 2-substituted-1,4,5,6-tetrahydrocyclopenta[b]pyrrole on TPA-induced skin inflammation in mice. Bioorganic & Medicinal Chemistry Letters 2016, 26 (21), 5334-5339.

　　18.Liu, W.-T.; Xu, Z.-L.; Mou, X.-Q.; Zhang, B.-H.; Bao, W.; Wang, S.-H.*; Lee, D.; Lei, L.-S.; Zhang, K., The synthesis of cycloalka[b]furans via an Au(i)-catalyzed tandem reaction of 3-yne-1,2-diols. Organic & Biomolecular Chemistry 2017, 15 (30), 6333-6337.

　　19.Zhang, B.-H.; Lei, L.-S.; Liu, S.-Z.; Mou, X.-Q.; Liu, W.-T.; Wang, S.-H.*; Wang, J.; Bao, W.; Zhang, K., Zinc-promoted cyclization of tosylhydrazones and 2-(dimethylamino)malononitrile: an efficient strategy for the synthesis of substituted 1-tosyl-1H-pyrazoles. Chemical Communications 2017, 53 (61), 8545-8548.

　　20.Zhang, X.-M.; Tu, Y.-Q.*; Zhang, F.-M.; Chen, Z.-H.; Wang, S.-H.*, Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis. Chemical Society Reviews 2017, 46 (8), 2272-2305.

　　21.Shao, H.; Bao, W.; Jing, Z.-R.; Wang, Y.-P.; Zhang, F.-M.; Wang, S.-H.*; Tu, Y.-Q.*, Construction of the [6,5,7,5] Tetracyclic Core of Calyciphylline A Type Alkaloids via a Tandem Semipinacol Rearrangement/Nicholas Reaction. Organic Letters 2017, 19 (17), 4648-4651.

　　22.Liu, L.; Cheng, H.-L.; Ma, W.-Q.; Hou, S.-H.; Tu, Y.-Q.*; Zhang, F.-M.; Zhang, X.-M.; Wang, S.-H.*, Improved synthesis of 8-oxabicyclo[3.2.1]octanes via tandem C-H oxidation/oxa-[3,3] Cope rearrangement/aldol cyclization. Chemical Communications 2018, 54 (2), 196-199.

　　23.吕卉, 徐., 黄丹颖, 吴盼盼, 盛钊君, 刘文锋, 李冬利, Njud S. Alharbi, 张焜, 王少华, 内质网荧光探针研究进展. 有机化学 2018, 38 (12), 3165-3175

　　24.Bao, W.; Wang, J.-Q.; Xu, X.-T.; Zhang, B.-H.; Liu, W.-T.; Lei, L.-S.; Liang, H.; Zhang, K.; Wang, S.-H.*, Copper-catalyzed cyclization of 2-cyanobenzaldehydes and 2-isocyanoacetates: an efficient strategy for the synthesis of substituted 1-aminoisoquinolines. Chemical Communications 2018, 54 (59), 8194-8197.

　　25.Liu, L.; Lei, L.-S.; Zhan, Z.-S.; Liu, S.-Z.; Wang, Y.-X.; Tu, Y.-Q.*; Zhang, F.-M.; Zhang, X.-M.; Ma, A.-J.; Wang, S.-H.*, A catalytic asymmetric one-pot [3+2] cyclization/semipinacol rearrangement sequence: an efficient construction of a multi-substituted 3H-spiro[benzofuran-2,1′-cyclopentane] skeleton. Chem. Commun. 2019, 55 (26), 3789-3792[1]

　　26.Lei, L.-S.; Xue, C.-G.; Xu, X.-T.; Jin, D.-P.; Wang, S.-H.*; Bao, W.; Liang, H.; Zhang, K.; Asiri, A. M., The synthesis of cyanoformamides via a CsF-promoted decyanation/oxidation cascade of 2-dialkylamino-malononitriles. Organic & Biomolecular Chemistry 2019, 17 (15), 3723-3726.

　　27.Xu, X.; Chen, J.; Lin, Z.; Li, D.; Zhang, K.; Sheng, Z.; Wang, S.*; Zhu, S.; Abdullah M. A. Synthesis and Anti-inflammatory Effects of Oxaprozin-Paeonol Ester[J]. Chinese Journal of Organic Chemistry, 2019, 39(10): 2958-2964.

　　28.Zhang, Y.; Zheng, T.-L.; Cheng, F.; Dai, K.-L.; Zhang, K.; Ma, A.-J.; Zhang, F.-M.; Zhang, X.-M.; Wang, S.-H.*; Tu, Y.-Q.* Facile access to diverse all-carbon quaternary center containing spirobicycles by exploring a tandem Castro–Stephens coupling/acyloxy shift/cyclization/semipinacol rearrangement sequence. Chemical Science 2020, 11, 3878-3884.

　　29.Bao, W.; Gao, Z.-P.; Jin, D.-P.; Xue, C.-G.; Liang, H.; Lei, L.-S.; Xu, X.-T.; Zhang, K.; Wang, S.-H.*, Direct synthesis of 2-substituted benzonitriles via alkylcyanation of arynes with N,N-disubstituted aminomalononitriles. Chem. Commun. 2020, 56 (55), 7641-7644.

　　30.Lei, L.-S.; Wang, B.-W.; Jin, D.-P.; Gao, Z.-P.; Huan, L.; Wang, S.-H.*; Xu, X.-T.; Zhang, K.; Zhang, X.-Y.*, Al(Otf)3-Catalyzed Tandem Coupling Reaction between N,N-Disubstituted Aminomalonitriles and Substituted Arenes: a Synthesis of 1-Cyano-bisindolylmethane Analogues≠. Advanced Synthesis & Catalysis 2020, 362 (14), 2870-2875.

　　31.Xu, X.-T.; Deng, X.-Y.; Chen, J.; Liang, Q.-M.; Zhang, K.; Li, D.-L.; Wu, P.-P.; Zheng, X.; Zhou, R.-P.; Jiang, Z.-Y.; Ma, A.-J.; Chen, W.-H.*; Wang, S.-H.*, Synthesis and biological evaluation of coumarin derivatives as α-glucosidase inhibitors. European Journal of Medicinal Chemistry 2020, 189, 112013.

　　32.Zheng, T.-L.; Zhang, Y.; Gou, A. L.; Cheng, F.; Liu, S.-Z.; Yu, L.*; Cui, M.-Y.; Xu, X.-T.; Zhang, K.; Wang, S.-H.*, Au(I)-Catalyzed Cyclization/Semipinacol Rearrangement Reaction of Allenes to Construct Quaternary Carbon-Containing Scaffolds. Organic Letters 2020, 22 (18), 7073-7077.

　　33.Liang, H.; Gou, A.; Gao, Z.; Lei, L.; Wang, B.; Yu, L.*; Xu, X.; Wang, S.*, A New Strategy for the Synthesis of Tertiary Amides via a Copper-Catalyzed Decyanation Reaction of N,N-Disubstituted 2-Aminomalononitriles. Acta Chim. Sinica 2020, 78, 1064.

　　34.Wang Shaohua, Z. B., Chen Jie, Zheng Yingying, Feng Na, Ma Aijun, Xu Xuetao, Abdullah M. Asiri, Recent Progress in Synthesis of Polysubstituted Pyrazoles. Chinese Journal of Organic Chemistry 2020, 40 (1), 15-27.

　　35.Zheng, T.-L.; Liu, S.-Z.; Huo, C.-Y.; Li, J.; Wang, B.-W.; Jin, D.-P.; Cheng, F.; Chen, X.-M.*, Zhang, X.-M.; Xu, X.-T.; Wang, S.-H.*, Au-Catalyzed 1,3-Acyloxy Migration/Cyclization Cascade: A Direct Strategy toward the Synthesis of Functionalized Abietane-Type Diterpenes. CCS Chem. 2020, 2, 2795-2802.

　　36.Liu, S.-Z.; Li, J.; Xue, C.-G.; Xu, X.-T.; Lei, L.-S.; Huo, C.-Y.; Wang, Z.; Wang, S.-H.*, Copper-promoted cyanation of aryl iodides with N,N-dimethyl aminomalononitrile. Tetrahedron Lett. 2021, 65, 152749.